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Science · Rates of reaction

Calculating a rate from a table

The table gives readings and you are unsure which numbers to divide.

Average rate is the change in the amount divided by the time taken. Pick the two rows that bound the interval, subtract, divide, and write the unit.

This lesson is part of rates of reaction. It puts numbers on the ideas in explaining collision ideas at Science depth.

How do I pick the numbers?

Decide the interval first, then read both the amounts and the times at its two ends. The change is the later amount minus the earlier amount, or the other way round when the mass falls.

Write the working as a fraction so the unit follows automatically: grams over seconds gives g per s.

Worked example: mass lost from an open flask

The table is original. A flask of acid and marble chips sits on a balance, and carbon dioxide escapes.

Time (s) 0 30 60 90 120 150
Mass (g) 85.00 84.46 84.10 83.90 83.80 83.80

Mass lost in each 30 s. Each interval uses the earlier mass minus the later mass.

  • 0 to 30 s: 85.00 − 84.46 = 0.54 g
  • 30 to 60 s: 84.46 − 84.10 = 0.36 g
  • 60 to 90 s: 0.20 g
  • 90 to 120 s: 0.10 g
  • 120 to 150 s: 0 g

Rates. Divide each mass lost by 30 s.

  • 0 to 30 s: 0.54 ÷ 30 = 0.018 g per s
  • 30 to 60 s: 0.36 ÷ 30 = 0.012 g per s
  • 60 to 90 s: 0.20 ÷ 30 = 0.0067 g per s
  • 90 to 120 s: 0.10 ÷ 30 = 0.0033 g per s
  • 120 to 150 s: 0 g per s

Reading. The rate falls each interval, and it is 0 from 120 s, so the reaction finished at about 120 s. The total mass lost is 1.20 g.

The mistake that costs marks

The common slip is to divide the total mass lost by the last time in the table. Here that gives 1.20 ÷ 150 = 0.008 g per s, which understates the rate while the reaction was running.

Step Wrong Right
Interval 0 to 150 s 0 to 120 s, where the reaction happened
Working 1.20 ÷ 150 1.20 ÷ 120
Answer 0.008 g per s 0.010 g per s
Unit (missing) g per s

If the question asks for the rate over 0 to 150 s, 0.008 is correct. Always check which interval the question names.

Checking your answer

Check two things. The rate should fall as time passes, and the units should match the table.

Also check the total. Adding the mass lost in each interval must give the final change: 0.54 + 0.36 + 0.20 + 0.10 + 0 = 1.20 g, which matches 85.00 − 83.80.

Check yourself

A gas syringe records 0 cm³ at 0 s, 14 cm³ at 20 s and 32 cm³ at 50 s. Find the average rate between 20 s and 50 s in cm³ per second, then in cm³ per minute.

Answer

Change in volume = 32 − 14 = 18 cm³. Change in time = 50 − 20 = 30 s.

Average rate = 18 ÷ 30 = 0.6 cm³ per second. To convert to minutes, multiply by 60: 0.6 × 60 = 36 cm³ per minute.

What to study next

Test all four lessons together with the rates of reaction practice set. If the subtraction step slips, return to reading rate graphs.

If you want a teacher to go through your working with you, see online one-to-one Science tuition.

Common questions

What is the formula for average rate?

Average rate = change in the amount ÷ time taken. The amount can be volume of gas formed, mass lost or mass of product. Write the unit as the amount unit per time unit, such as cm³ per second.

Why does the rate differ between intervals?

The reaction is fastest at the start when the reactants are most plentiful and slows as they are used up. Each interval has its own average rate, so the numbers fall as time goes on.

Should I divide by the total time shown in the table?

Only when the question asks for the rate over the whole record. If the reaction has finished, the flat part adds time but no change, so the average is lower than the rate while it was reacting.

How do I handle a mass that goes down?

Subtract the later mass from the earlier one to find the mass lost, which is always positive. Then divide by the time. A gas escaping from an open flask causes the mass loss.

If you slip on the subtraction or the units, one-to-one Science lessons let a teacher check your working line by line and name the exact step that goes wrong.

  • Online one-to-one lessons for your child with an experienced teacher.
  • Your first class is a one-hour trial, from RM50. The fee is agreed before you book.
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